One-pot formation of hydrazide macrocycles with modified cavities: An example of pH-sensitive unimolecular cation channels

Pengyang Xin; Si Tan; Yonghui Sun; Qiaojv Ren; Wenpei Dong; Jingjing Guo; Tao Jiang; Chang Po Chen

doi:10.1039/c7cc02076g

One-pot formation of hydrazide macrocycles with modified cavities: An example of pH-sensitive unimolecular cation channels

Pengyang Xin, Si Tan, Yonghui Sun, Qiaojv Ren, Wenpei Dong, Jingjing Guo, Tao Jiang, Chang Po Chen

Henan Normal University

Research output: Contribution to journal › Article › peer-review

7 Citations (Scopus)

Abstract

A series of pH-sensitive, cation-selective hydrazide macrocyclic channels have been synthesized. The macrocyclic channels bear multiple carboxyls in the inner cavity, which have a significant impact on their membrane-incorporation ability and NH₄⁺ transport activity. Moreover, the K⁺/Cl^- selectivities of the macrocyclic channels can be tuned by the pH value of the electrolyte.

Original language	English
Pages (from-to)	5322-5325
Number of pages	4
Journal	Chemical Communications
Volume	53
Issue number	38
DOIs	https://doi.org/10.1039/c7cc02076g
Publication status	Published - 2017
Externally published	Yes

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title = "One-pot formation of hydrazide macrocycles with modified cavities: An example of pH-sensitive unimolecular cation channels",

abstract = "A series of pH-sensitive, cation-selective hydrazide macrocyclic channels have been synthesized. The macrocyclic channels bear multiple carboxyls in the inner cavity, which have a significant impact on their membrane-incorporation ability and NH4+ transport activity. Moreover, the K+/Cl- selectivities of the macrocyclic channels can be tuned by the pH value of the electrolyte.",

author = "Pengyang Xin and Si Tan and Yonghui Sun and Qiaojv Ren and Wenpei Dong and Jingjing Guo and Tao Jiang and Chen, {Chang Po}",

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T2 - An example of pH-sensitive unimolecular cation channels

AU - Xin, Pengyang

AU - Tan, Si

AU - Sun, Yonghui

AU - Ren, Qiaojv

AU - Dong, Wenpei

AU - Guo, Jingjing

AU - Jiang, Tao

AU - Chen, Chang Po

PY - 2017

Y1 - 2017

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AB - A series of pH-sensitive, cation-selective hydrazide macrocyclic channels have been synthesized. The macrocyclic channels bear multiple carboxyls in the inner cavity, which have a significant impact on their membrane-incorporation ability and NH4+ transport activity. Moreover, the K+/Cl- selectivities of the macrocyclic channels can be tuned by the pH value of the electrolyte.

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M3 - Article

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AN - SCOPUS:85021665616

SN - 1359-7345

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JO - Chemical Communications

JF - Chemical Communications

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ER -

One-pot formation of hydrazide macrocycles with modified cavities: An example of pH-sensitive unimolecular cation channels

Abstract

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