Nickel–Copper Alloy Encapsulated in Graphitic Carbon Shells as Electrocatalysts for Hydrogen Evolution Reaction

Yi Shen, Yongfang Zhou, Duo Wang, Xi Wu, Jia Li, Jingyu Xi

研究成果: Article同行評審

237 引文 斯高帕斯(Scopus)

摘要

Searching for cost-effective and high-performance electrocatalysts for hydrogen production is of paramount importance. Herein, nickel-copper (NiCu) alloy nanoparticles are encapsulated into graphitic shells via an ambient-pressure chemical vapor deposition process. The resulting carbon-encapsulated NiCu (denoted as NiCu@C) composite possesses a well-defined core–shell structure with tunable thicknesses of the shells and is examined as electrocatalysts for the hydrogen evolution reaction (HER) in acidic, neutral, and alkaline solutions. Electrochemical measurements indicate that the activity of the NiCu@C highly depends on the thickness of the shell. Single-layered graphene encapsulated NiCu nanoparticles show remarkable HER activity and durability. To obtain a current density of 10 mA cm−2, overpotentials of 48, 164, and 74 mV are needed in electrolyte solutions with pH = 0, 7, and 14, respectively. Such low overpotentials render the composite as one of the most active nonprecious electrocatalysts. Accelerated durability tests demonstrate that the NiCu@C catalysts exhibit excellent stability. Density function theory calculations are conducted to investigate the electronic structures of the NiCu@C. It is found that the representative Ni43Cu12@C240 model shows an ideal adsorption energy of hydrogen (−0.03 eV), manifesting its high HER activity.

原文English
文章編號1701759
期刊Advanced Energy Materials
8
發行號2
DOIs
出版狀態Published - 15 1月 2018
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